8/31/2023 0 Comments Group 7 reactivity trendThe process is assumed to start from the solid sodium halide. The table below shows the energy changes that vary from halogen to halogen. The total enthalpy change is the sum of the enthalpy changes for the halide ion half-reaction and the sulfuric acid half-reaction. That is the same irrespective of the halogen in question. Heat is emitted when the changes involving the sulfuric acid occur. This is not the total enthalpy change for the whole reaction. The diagram shows that the overall change involving the halide ions is endothermic (the green arrow is pointing up toward a higher energy). The enthalpy change shown by the green arrow in the diagram for each of the halogens must be compared. The figure below shows how this information fits together: The value of interest is the reverse of atomization energy.Ītomization energy is the energy needed to produce 1 mole of isolated gaseous atoms starting from an element in its standard state (gas for chlorine, and liquid for bromine, for example - both of them as X 2). To account for this, it is simpler to think in terms of atomization energy rather than bond energy. In bromine and iodine, heat is also released during condensation to a liquid or a solid, respectively. Energy is released when these bonds are formed. The energy recovered when the chlorine atoms convert to diatomic chlorine.This is the reverse of the electron affinity of the chlorine (the electron affinity can be acquired from a data table and negated). The energy required to remove the electron from the chloride ion.The energy required to break the attractions between the ions in the sodium chloride (the lattice enthalpy).Taking sodium chloride as an example, the following energetic quantities are important: The amount of heat evolved or absorbed when a solid halide (like sodium chloride) is converted into an elemental halogen must be considered. Hydrogen sulfide gas can be detected by its "rotten egg" smell, but this gas is intensely poisonous.Įnthalpy change variation between halogens The red color is due to the I 3 - ion formed by reaction between I 2 molecules and I - ions. There is also a red color where the iodine comes into contact with solid iodide salts. The reaction is exothermic: purple iodine vapor is formed, with dark gray solid iodine condensing around the top of the reaction vessel. This is confirmed by a trace of steamy fumes of hydrogen iodide and a large amount of iodine. The half-equation for its formation is as follows:Ĭombining these two half-equations gives the following net ionic equation: ![]() The most abundant product is hydrogen sulfide. sulfur to hydrogen sulfide (sulfur oxidation state = -2).sulfur dioxide to elemental sulfur (oxidation state = 0). ![]() ![]()
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8/31/2023 0 Comments Webscraper chrome fill out formsOnce you have a clearer picture of your requirements, it should be easier to match them against the available technologies and platforms and pick the most appropriate tool for your particular scraping job.Īll right, let's now take a closer look at the different types of web scrapers and popular representatives of each category. Platform Requirements - how well does a scraper integrate into your infrastructure and workflows? Does it support the existing operating system? Are there interfaces to third party services and APIs you may want to use?.In-House Expertise - how much effort will it be for you to create the scraper setup and maintain it? How far would you like to venture into custom application code?.Scraping Obstacles - is the site you want to scrape employing any security layers to block crawlers and scrapers? Will you need to solve CAPTCHAs? Do you need to take into account rate limits? Do you need to send the request from a particular location - or maybe even need to rotate networks?.Site Complexity - how straightforward is the site to scrape? Are you going to handle server-composed HTML documents, or will it rather be a more complex Single-page application with lots of JavaScript interaction?. ![]() a sitemap) or is it necessary to crawl the whole page? May search engines be useful in finding new pages (i.e. Crawling Authority - how would you find out about additional links? Does the site link all of its URLs from a central page (e.g.Scraping Scope - do you need to scrape only a couple of pre-set pages or do you need to scrape most or all of the site? This part may also determine whether and how you need to crawl the site for new links.Data Volume - how much data are you going to extract? Will it be a couple of bytes or kilobytes or are we talking about giga- and terabytes?.Data Export - how do you wish to receive the data? In its original raw format? Pre-processed, maybe sorted or filtered or already aggregated? Do you need a particular output format, such as CSV, JSON, XML, or maybe even imported into a database or API?.Data Input - what kind of data are you going to scrape? HTML, JSON, XML, something binary, like DOCX - or maybe even media, such as video, audio, or images?.Scraping Intervals - how often do you need to extract information? Is it a one-off thing? Should it happen regularly on a schedule? Once a week? Every day? Every hour? Maybe continuously?.So, before we simply jump in at the deep end, let's establish a few key parameters for our scraping project, which should help us narrow down the list of potential scraping solutions. Many of us like to play Dart □, but we shouldn't necessarily pick our scraping platform (or technology) like that, right? Please feel free to check it out, should you wish to learn more about web scraping, how it differs from web crawling, and a comprehensive list of examples, use cases, and technologies. ℹ️ We have a lovely article, dedicated to this very subject - What is Web Scraping. Jobs - aggregation of open vacancies from company websites and job boards.Finance - monitoring the performance of stocks and commodities.E-commerce - comparing prices of products across different online online shops. ![]() They continuously crawl and scrape the web for new and updated content, to include in their search index. Scrapers come in many shapes and forms and the exact details of what a scraper will collect will vary greatly, depending on the use cases.Ī very common example is search engines, of course. Web scraping is all about collecting content from websites. We'll be taking a closer at the tools, both commercial and open-source, available in the data scraping and data extraction landscape and elaborate on their features and how you may use them best for your particular use case. That's exactly what we want to check out in today's article. With such a large number, it, unfortunately, is not always easy to quickly find the right tool for your very own use case and to make the right choice. At the same time, you will find a myriad of services and tools, which want to help you in your endeavor. When you need to extract information from the web, you will inevitably come across the term "web scraping". 8/31/2023 0 Comments 3d vs 4d nippleConsultation and Diagnose for Hormones, Bones, etc. ![]() Help and Training for Breastfeeding Skills to New Mothers.Help and Support for unwilling-to-nurse babies or nipple confusions.Help and Support for insufficient breast milk or low milk supply.Help and Support for Breastfeeding Problems.Help and Support for Breastfeeding Preparation.Help and Support for Breast and Nipple Problems such as engorged breasts, breast infections, or sore nipples.Consultation on the phone for breastfeeding.Consultation and Planning for Birth Control.” Breastfeeding is recommended up to 6 months of age with the well-trained expertise.” Standardized and Advanced Technology for Childbirth.Service for Delivery Compensation from Social Security Office.Service for Birth Registration and Birth Certification for Thais and Foreigners.Neonatal Critical Care by Newborn Specialist with the advanced technology.Individually Pediatrician for Every Newborn Baby.High-Risk Pregnancy Care by Obstetrician and Pediatrician.High-risk Pregnancy Screening for example, Gestational Diabetes, Anemia, Thalassemia, High Blood Pressure in Pregnancy, Thyroid, Pregnancy After Age 35, including the planning for high-risk pregnancy care continuously.Preparing for Pregnancy Training both Thais and Foreigners by Obstetrician (free of charge).Prenatal Medical Care opens daily at 8.00-20.00 hrs.Personal obstetrician for pregnancy, childbirth, and postnatal care.Genetic Testing for High Risk Pregnancy.Breastfeeding clinic provides the breast check-up and consultation of breastfeeding preparation and problems for 24 hours.Pregnancy Planning (premarital and pre-pregnancy).Urinary Incontinence (Overactive Bladder)Ĭomprehensive Maternity Care and Childbirth.Sexually Transmitted Diseases in Women (STDs).Consultation and Surgery for Reversal of Female Sterilization (in case of wanting more child).Infertility Treatments (Fertility Clinic) Other Diagnoses and Treatments Menstrual Cramps (Dysmenorrhoea) Diagnosis and Treatment.Lower Abdominal Pain Diagnosis and Treatment.Frequent Urination (Urinary Frequency) Diagnosis and Treatment.Endometriosis or Chocolate Cyst Diagnosis and Treatment. ![]() Ectopic Pregnancy Diagnosis and Treatment.Diagnosis for Infertility or Recurrent Abortion.Ultrasound Diagnosis for Ovarian Cancer and Tumor Marker.Thin Prep Test for Cervical Cancer Screening (HPV Screening).Obstetrics and Gynecologic Ultrasound for Pelvic Examination in order to find out Myoma or Cyst.Loop Electrosurgical Excision Procedure (LEEP).Both are designed to highlight the beauty of our procedures that restore feminine form. Colposcopy Screening for Cervical Cancer The nipple may be recreated using either 3D or 4D technique. ![]()
8/31/2023 0 Comments Ww2 gas mask photos![]() Food chain owned by millionaire supermarket tycoon is caught 'selling meat 13 days past its use-by date' in fresh controversy for boss slammed for 'Grand Designs' planning row and flying his helicopter by Heathrow.More than 13,000 migrants have crossed the Channel by small boat so far this year - with 338 people intercepted yesterday alone.'Headless' child's body is found on a Spanish beach.Moment Noel Gallagher's ex-wife Meg Mathews, 57, is bundled into back of a police van for 'drunkenly crashing her car into a stationary vehicle' after book launch.Police fear little Emile, two, is dead and his body 'hidden after an accident with a car or tractor' in chilling echo of BBC series The Missing - as his mother's voice is broadcast from choppers in bid to draw him out.British tourist, 27, drowns in Algarve hotel pool during family holiday.Aspiring actors were aware of 'rumours' about Kevin Spacey's sexual advances on young men while he worked in the UK, Hollywood actor's sex assault trial hears.Carrie Johnson has given birth to third child with Boris: Ex-PM's wife reveals she has had a second son named 'Frank Alfred Odysseus' (or Frankie for short) in adorable Instagram snap.Russian general known personally by Putin is killed 'by British-supplied Storm Shadow missile'.Russia warns it will take 'appropriate' measures in response to Sweden joining NATO - as Zelensky declares it will be 'absurd' if Ukraine's bid is not given a firm timetable.US man's tongue turns green and hairy after rare reaction to cigarettes and antibiotics.As Carrie and Boris Johnson welcome their third child together, how the couple have chosen baby names with special significance - from family tributes to Greek words.Shocking moment motorist pushes woman off her mobility scooter after she smashes into his Mercedes in road rage row.Prolific robber, 24, who suffered a broken leg and police dog bite after being deliberately knocked off a stolen motorbike as he tried to flee is 'suing police for his injuries'.Dog dies less than 45 minutes after coming into contact with blue-green algae in first confirmed case of its kind - as Kennel Club issues warning to owners.Titanic Five knew their fate for a MINUTE before vessel 'popped like balloon', claims expert: Victims would have felt 'horror, fear and agony as the five men piled on top of each other during 3,000ft nosedive'.Prime Day 2023 UK LIVE: Best Amazon deals on everything from Ninja Air Fryers to Kindle Paperwhite.Cancer-stricken British tech boss dies aged 43 just months after he set up children's charity: Millionaire Nutmeg co-founder passes away after battle with bone cancer - leaving behind his wife and toddler daughter.Europe braces for record-breaking heatwave: Tourists faint in Italy as Mediterranean approaches its highest temperatures EVER and Brits are warned to prepare for sweltering 48C in holiday hotspots.Bombshell new claims about BBC star at centre of '£35k sex pics' scandal: Presenter 'sent abusive and menacing messages to SECOND young person - who threatened to name him after they met on dating app'. 8/31/2023 0 Comments Air max 90 pink volt![]() Shoppers 24/7, shop this collection online today. 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To learn more about how and for what purposes Amazon uses personal information (such as Amazon Store order history), please visit our Privacy Notice.Browse and find the latest Nike footwear, clothing and accessories on Studio 88. You can change your choices at any time by visiting Cookie Preferences, as described in the Cookie Notice. Click ‘Customise Cookies’ to decline these cookies, make more detailed choices, or learn more. The Air Max 90 served as a great performance running shoe that featured a midsole whose stability had been unseen before. Third parties use cookies for their purposes of displaying and measuring personalised ads, generating audience insights, and developing and improving products. If we don't, snowpack could shrink by 90 percent, ending most winter. This includes using first- and third-party cookies, which store or access standard device information such as a unique identifier. Smoggier mountain skies Rising temperatures could worsen air quality in New. If you agree, we’ll also use cookies to complement your shopping experience across the Amazon stores as described in our Cookie Notice. We also use these cookies to understand how customers use our services (for example, by measuring site visits) so we can make improvements. We use cookies and similar tools that are necessary to enable you to make purchases, to enhance your shopping experiences and to provide our services, as detailed in our Cookie Notice. 8/31/2023 0 Comments Degree of freedom in statistics![]() They are commonly discussed in relationship to various forms of hypothesis testing in statistics, such as a. In statistics, the degrees of freedom tells you how many independent values that can vary without breaking any constraints in the problem. State the general formula for degrees of freedom in terms of the number of values and the number of estimated parameters. State why deviations from the sample mean are not independent. $SSE:$ $(n-1)-(p-1)=n-p$, which follows linearity of $df$. Degrees of freedom are the number of values in a study that have the freedom to vary. Although most of the statistical tests encountered during a course on inferential. Estimate the variance from a sample of 1 if the population mean is known. However note that this will equal the number of parameters when we are doing regression with multiple parameters. For any given study, always try to test more subjects to increase precision (ie. Degrees of freedom are important in a Chi-square test because they factor into your calculations of the probability of independence. T distributions with more degrees of freedom approximate the Normal distribution more closely. I checked up a t-distribution table and found that the degrees of freedom went upto 120. I wanted to provide a rigorous answer that starts from a concrete definition of degrees of freedom for a statistical estimator as this may be useful/satisfying to some readers:ĭefinition: Given an observational model of the form $$y_i=r(x_i)+\xi_i,\ \ \ i=1,\dots,n$$ where $\xi_i=\mathcalX^T)$$ $$=p-1.$$ In your case $p=2$ since you will want $X$ to include the all ones vector so that there is an intercept term, and so the degrees of freedom will be $1$. Degrees of freedom refers to the number of pieces of information that are available, and are determined by sample size. It is an essential idea that appears in many contexts throughout statistics including hypothesis tests, probability distributions, and linear regression. There are many different ways to look at degrees of freedom. The degrees of freedom (DF) in statistics indicate the number of independent values that can vary in an analysis without breaking any constraints. 8/31/2023 0 Comments Infographic cv template![]() IMPLIED, INCLUDING BUT NOT LIMITED TO THE WARRANTIES OF MERCHANTABILITY,įITNESS FOR A PARTICULAR PURPOSE AND NONINFRINGEMENT. THE SOFTWARE IS PROVIDED "AS IS", WITHOUT WARRANTY OF ANY KIND, EXPRESS OR To use, copy, modify, merge, publish, distribute, sublicense, and/or sellĬopies of the Software, and to permit persons to whom the Software isįurnished to do so, subject to the following conditions: In the Software without restriction, including without limitation the rights Of this software and associated documentation files (the "Software"), to deal Permission is hereby granted, free of charge, to any person obtaining a copy ❤️ Thanks a lot to all sponsors of this project, your contribution will help to keep this project going: You want to contribute? Awesome! 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You can also hold the word and rearrange them.If make a mistake, need click on the word to delete it.On the site, you need to click on any word to add it to your answer. But instead of typing their answers, players should use the words of fellow interviewers to answer questions. In the first round called "icebreaker" will ask questions, answering as simply as possible with at least 5 words.Īfter the "icebreaker" in the first round comes the "interview" where difficult interview questions are asked. Bubbles, the manager, has developed a revolutionary new hiring process in which they will interrogate everyone at once and force them to judge each other. Players who have entered the game become each other's colleagues who have applied for this employment opportunity. Job Job is the first game to be announced for The Jackbox Party Pack 8, having been announced on April 29, 2021. You’re more likely to fall asleep at the wheel. ![]() This can be downright dangerous when it comes to things like driving. You’re fatigued because you’re waking up constantly. It can also lead to an increased likelihood of developing depression. Lack of sleep causes problems with memory and can make you confused throughout the day. Letting sleep apnea go untreated can impact your health severely. Finding your perfect fit allows you to breathe through your mouth throughout the entire night with no restrictions. The shorter the strap is, the farther your mandible is advanced. This allows each patient to find the perfect option for them. To do this, the device offers nine different strap lengths and four different elastic tension options. This helps open up your airflow and avoids restriction of your breathing throughout the night. It gets its name from the fact that it advances the mandible to a different position, therefore opening your bite. This is a customizable and removable appliance that you wear while you’re sleeping. What is the EMA Sleep Appliance?ĮMA stands for Elastic Mandibular Advancement. An oral appliance is discreet and more cost-effective as well, making it a quality option for many sleep apnea sufferers. It situates your mouth and tongue so that you’re able to breathe freely throughout the night. It prevents the tongue from collapsing and blocking your airway while you’re sleeping. Wearing an oral appliance is similar to wearing a customized mouthguard. An oral appliance offers a much more comfortable treatment solution for many patients. The CPAP machine is large and hard to travel with, as well as uncomfortable for many users to wear. Typically, the CPAP machine was the designated device for sleep apnea. William Harper explains the EMA sleep appliance and how it works to assist your sleep apnea. It all depends on the specific patient and how their particular case reacts to a certain treatment. There are a variety of appliances we can use. The lab will need upper and lower models poured in die stone with pencil marks on crowns, implants and sensitive teeth.At Coastal Virginia Sleep Solutions, we focus on oral appliance therapy for the treatment of sleep apnea in Chesapeake, VA. Bite Techniqueīite open 8 mm incisally, with hinge open from centric. The EMA sleep apnea and snoring appliance is FDA and ADA approved and has been in use since 1995. The freedom of movement of the mandible significantly reduces the occurrence of temporomandibular joint dysfunction and pain. Left-to-Right Mobility Bands of varying elasticity move the lower mandible forward into the desired position while continuing to allow the jaw to move in all directions. The flexibility of the elastic bands allows for individualization of your patient's treatment and the ability for quick and easy adjustments to provide optimum results. This design allows the gradual advancement of the mandible until treatment is successful.ĭesign innovation includes the precise regulation of the amount of advancement and freedom of mandibular motion. ![]() Our Elastic Mandibular Advancement oral device or EMA for sleep apnea is a patient-friendly patented design using interchangeable elastic straps attached to pressure-formed custom upper and lower trays for the treatment of Sleep Apnea. 8/31/2023 0 Comments Bijou theater chicago closingAccording to Deadline, the two-time Emmy winner is the first Black (and, certainly, Black gay) director to sweep. Videos below - As the Emmy nominations were announced (with Succession leading with 27 noms), openly gay Paris Barclay made history. SHOWBIZ Emmys, 'Top Chef,' Hyphen Hyphen, Da Brat, 'Transparent,' Ben Cohen The Sarah Siddons Society will present the Swell Soiree-an evening of cabaret performances celebrating The Great American Songbook-on Wed., Aug. 16 at The Den Theatre (Upstairs Mainstage), 1331 N. Hell in a Handbag Productions will conclude its 21st season with the world-premiere musical parody Murder, ReWrote, playing Aug. Musical parody 'Murder, Rewrote' to run Aug. Pictures Group co-chair/CEO Pamela Abdy an. Queer, Oscar-winning performer/actor Ariana DeBose became one of three people who have joined the American Film Institute's board of trustees, The Hollywood Reporter noted. SHOWBIZ Ariana DeBose, Outfest, 'Gay Days,' 'Drag Race,' Keke Palmer The Bijou has never been pretty it has always been deliciously nasty and I'll keep it that way till I'm done, then I'll turn off the lights and go home." It is what sex was in the 1970s and '80s. "There is nothing in the world like the Bijou. People are still coming out at the Bijou, we have a lot of return customers, regulars, married men, tourists who come to the big city to experience what they would never do back home, people who want to see porn in a sexual environment with other men, people that want anonymous sex. We're always getting in new people from Chicago who have heard of us, seen our ads. "The Bijou is too intimidating young men have to get to know themselves better. "The Bijou customer, since the first day I opened the theater, has never been young, the 18-to-25-year-old crowd," Toushin said. He told Windy City Times in 2011 that the previous five years had been difficult, given the advent of Internet pornography and a reduced amount of convention business in the city. He has had a number of legal skirmishes over the years, including a conviction for tax evasion in the late '80s and a number of obscenity indictments. Toushin was put in charge of the Bijou in 1970 the venue began showing gay films exclusively in 1978. I received vacation and sick pay places that do that for a part-time job, I imagine, are few and far between these days."īijou World, Toushin's mail-order and online video business, will remain open, but Toushin said he did not yet know where it will relocate to. They were gay-friendly, lesbian-friendly and trans-friendly there. He said, "I got to see the gay community evolve in that place. "We appreciate and thank the gay community, and have been grateful to be a part of it for 46 years."Īctivist Michael O'Connor has had a part-time job at the theater for several years, and said he'll miss it. "I'm working with David Boyer at Touche to put together something for the last week so that we can go out on a high note," he said. When reached for comment, Toushin told Windy City Times that he had "little to add" beyond the message. "I wanted to have a bit more time if I was going to close down after all these years." "It's not the way I wanted to go out," he said. ![]() Ownership changes of buildings and leases change."īijou cannot move because its license is tied to the location, he added. "The end of days has come to Bijou after 46 years," Toushin said in the message. ![]() Its last full 24-hour day of operation will be Sept. 30.Īccording to a recorded message left by owner Steve Toushin at the theater's phone number, Bijou lost its lease at its longtime Old Town location. This article shared 25832 times since Fri Sep 11, 2015īijou Theater, 1349 N. |
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